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You have selected a combination of two ions, of
which at least one is polyatomic. The formula overall is not charged, but
the internal pieces are, and the name of the compound is based on those
component ions.
The charge of each ion is not seen directly. It is hidden in the formula but
is reflected in the grouping of the bonded parts. For example the charge of
S in the formula (NH4)2S
is -2 which
is not shown but is reflected in the number of ammonium NH4 ions
bonded to S, which is 2.
See the (NH4)2S
example at the bottom of this page.
Naming Inorganic Compounds: Try a new formula
Click here to see the Legend. See also: typical oxidation numbers
The positive ion must appear first (on the left).
![]() name |
place a space in between |
![]() name |
This naming scheme does not require any Greek Numerals on multiple instances of the same atom.
Comments:
The number of repetitions of
identical-s does not play a role in the naming.
Do not use Greek numerals. For example, The
2
in
(NH4)2
in the example below is not noted
in the name.
When composing the
polyatomic name,
don't use the word ion. For ex. NH4 = ammonium
is used
rather than "ammonium ion" in the naming of the formula.
If one of the
-s
is complex, the other one
can either be complex, or a simple ion, like
Cl-
in NH4Cl for example.
Examples:
We see these as two distinct ions but we do not use the word "ion" in the naming scheme. | ||||||
Formula |
![]() |
![]() |
Overall name | |||
NH4Cl | NH4 + = ammonium | Cl- = chloride | ammonium chloride | |||
(NH4)2S | NH4 + = ammonium | S2- = sulfide | ammonium sulfide | |||
(NH4)2CrO4 | NH4 + = ammonium | CrO4 = chromate | ammonium chromate | |||
Cl2 | Exception: we do not use the word ion in the naming, we take the name of the element from the periodic table as is. | chlorine Convention: The name is the elemental name: chlorine because Cl2 it is a neutral diatomic molecule. |
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More examples of two atoms of the same
elements in the molecule are: hydrogen (H2), nitrogen (N2), oxygen (O2), fluorine (F2), bromine (Br2), iodine (I2). |
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